Safety Data Sheet dated 3/12/2014, version 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Mixture identification:
Trade name: 	Air horn
Trade code: 	4555
1.2. Relevant identified uses of the substance or mixture and uses advised against
	Description/Use:	       Pwerful air horn
1.3. Details of the supplier of the safety data sheet
Company: 
DAC SRL

Sede legale - head office and legal address:  
Via Libero Grassi, 4 – 42025 Cavriago (RE)
Sede amministrativa e logistica/magazzino-administration and logistic/warehouse address: 
Viale J.F. Kennedy 21/A - 46019 – Viadana – MN (ITALY)
Tel. +39 0375 820611 centralino  -  Fax +39 0375 785840 
Mail: dac.info@dacsrl.net     Web: www.dacsrl.net      
P.IVA/VAT: 02675390351 - Numero REA: RE-303424 
1.4. Emergency telephone number +39 0375 820611

SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
Properties / Symbols:
F+ Extremely flammable
R Phrases:
R12 Extremely flammable.

EC regulation criteria 1272/2008 (CLP):

  Danger, Aerosols 1, Extremely flammable aerosol. Pressurized container: may burst if heated.

Adverse physicochemical, human health and environmental effects: 
No other hazards
2.2. Label elements
Symbols:

Danger
Hazard statements:
H222+H229 Extremely flammable aerosol. Pressurized container: may burst if heated.
Precautionary statements:
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50 °C/122°F.
Special Provisions:
None
Special provisions according to Annex XVII of REACH and subsequent amendments:
None
2.3. Other hazards
vPvB Substances: None - PBT Substances: None
Other Hazards:
No other hazards

SECTION 3: Composition/information on ingredients
3.1. Substances
N.A.
3.2. Mixtures
Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and related classification:
>= 50% - < 60% propane
Index number: 601-003-00-5, CAS: 74-98-6, EC: 200-827-9
F+; R12

  2.2/1 Flam. Gas 1 H220

  2.5 Press. Gas H280

>= 25% - < 30% butane
Index number: 601-004-00-0, CAS: 106-97-8, EC: 203-448-7
F+; R12

  2.2/1 Flam. Gas 1 H220

  2.5 Press. Gas H280

>= 10% - < 12.5% butane
Index number: 601-004-00-0, CAS: 75-28-5, EC: 200-857-2
F+; R12

  2.2/1 Flam. Gas 1 H220

  2.5 Press. Gas H280

SECTION 4: First aid measures
4.1. Description of first aid measures
In case of skin contact:
Wash with plenty of water and soap.
In case of  eyes contact:
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
In case of Ingestion:
Do NOT induce vomiting.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
4.2. Most important symptoms and effects, both acute and delayed
None
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: 
None

SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media:
In case of fire, use dust fire extinguisher, CO2 or foam.
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3. Advice for firefighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.

SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove all sources of ignition.
Remove persons to safety.
See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13

SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals in the containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Keep away from unguarded flame, sparks, and heat sources.  Avoid direct exposure to sunlight.
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Cool and adequately ventilated.
7.3. Specific end use(s)
None in particular

SECTION 8: Exposure controls/personal protection
8.1. Control parameters
butane - CAS: 106-97-8
	 ACGIH, 1000 ppm - Notes: CNS impair
butane - CAS: 75-28-5
	 ACGIH, 1000 ppm - Notes: CNS impair
DNEL Exposure Limit Values
N.A.
PNEC Exposure Limit Values
N.A.
8.2. Exposure controls
Eye protection:
Not needed for normal use. Anyway, operate according good working practices.
Protection for skin:
No special precaution must be adopted for normal use.
Protection for hands:
Not needed for normal use.
Respiratory protection:
Not needed for normal use.
Thermal Hazards:
None
Environmental exposure controls:
None

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
	Appearance and colour:	       Limpid colourless
Odour threshold:	Odourless
pH:	N.a.
Melting point / freezing point:	N.A.
Initial boiling point and boiling range:	N.A.
Solid/gas flammability:	N.A.
Upper/lower flammability or explosive limits:	N.A.
Vapour density:	N.A.
Flash point:	< 0 ° C
Evaporation rate:	N.A.
Vapour pressure:	N.A.
Relative density:	0,55 gr/ml c.ca
Solubility in water:	Partial
Lipid solubility:	Soluble
Partition coefficient (n-octanol/water):	N.A.
Auto-ignition temperature:	N.A.
Decomposition temperature:	N.A.
Viscosity:	N.A.
Explosive properties:	N.A.
Oxidizing properties:	N.A.
9.2 Other information
Miscibility:	N.A.
Fat Solubility:	N.A.
Conductivity:	N.A.
Substance Groups relevant properties	N.A.

SECTION 10: Stability and reactivity
10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
It may catch fire on contact with oxidising mineral acids.
10.4. Conditions to avoid
Stable under normal conditions.
10.5. Incompatible materials
Avoid contact with combustible materials.  The product could catch fire.
10.6. Hazardous decomposition products
None.

SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicological information of the mixture:
N.A.
Toxicological information of the main substances found in the mixture:
N.A.
If not differently specified, the information required in Regulation 453/2010/EC listed below must be considered as N.A.:
a) acute toxicity;
b) skin corrosion/irritation;
c) serious eye damage/irritation;
d) respiratory or skin sensitisation;
e) germ cell mutagenicity;
f) carcinogenicity;
g) reproductive toxicity;
h) STOT-single exposure;
i) STOT-repeated exposure;
j) aspiration hazard.

SECTION 12: Ecological information
12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.
N.A.
12.2. Persistence and degradability
None
N.A.
12.3. Bioaccumulative potential
N.A.
12.4. Mobility in soil
N.A.
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
None

SECTION 13: Disposal considerations
13.1. Waste treatment methods
Recover, if possible.  Send to authorised disposal plants or for incineration under controlled conditions.  In so doing, comply with the local and national regulations currently in force.

SECTION 14: Transport information
14.1 UN number:
ADR-UN number:	1950
IATA-UN number:	1950
14.2 UN proper shipping name:
ADR-Shipping Name:	Aerosol with capacity of 1000 cm3 0r less
14.3 Transport hazard class(es): 
ADR-Class:	2 
ADR-Label:	UN 1950 Aerosols
IATA-Class:	2.1
IMO-Class:	2.1
14.4 Packing Group:
ADR-Packing Group:	III 
14.5 Environmental hazards
N.A.
14.6 Special Precautions for User
N.A.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No

SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances)
Dir. 99/45/EC (Classification, packaging and labelling of dangerous preparations)
Dir. 98/24/EC (Risks related to chemical agents at work)
Dir. 2000/39/EC (Occupational exposure limit values)
Dir. 2006/8/EC
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) n. 453/2010 (Annex I)
Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 618/2012 (ATP 3 CLP)
Regulation (EU) n. 487/2013 (ATP 4 CLP)
Regulation (EU) n. 944/2013 (ATP 5 CLP)
Regulation (EU) n. 605/2014 (ATP 6 CLP)
Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH) and subsequent modifications:
Restrictions related to the product:
Restriction 3
Restriction 40
Restrictions related to the substances contained:
No restriction.
Where applicable, refer to the following regulatory provisions :
Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent amendments.
Regulation (EC) nr  648/2004 (detergents).
1999/13/EC (VOC directive)

Provisions related to directives 82/501/EC(Seveso), 96/82/EC(Seveso II): 
		N.A.
15.2. Chemical safety assessment
No

SECTION 16: Other information
Text of phrases referred to under heading 3:
R12 Extremely flammable.

H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.
This safety data sheet has been completely updated in compliance to Regulation 453/2010/EU.
This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
CCNL - Appendix 1
Insert further consulted bibliography
The information contained herein is based on our state of knowledge at the above-specified date.   It refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This MSDS cancels and replaces any preceding release.

ADR:	European Agreement concerning the International Carriage of Dangerous Goods by Road.	
CAS:	Chemical Abstracts Service (division of the American Chemical Society).	
CLP:	Classification, Labeling, Packaging.	
DNEL:	Derived No Effect Level.	
EINECS:	European Inventory of Existing Commercial Chemical Substances.	
GefStoffVO:	Ordinance on Hazardous Substances, Germany.	
GHS:	Globally Harmonized System of Classification and Labeling of Chemicals.	
IATA:	International Air Transport Association.	
IATA-DGR:	Dangerous Goods Regulation by the "International Air Transport Association" (IATA).	
ICAO:	International Civil Aviation Organization.	
ICAO-TI:	Technical Instructions by the "International Civil Aviation Organization" (ICAO).	
IMDG:	International Maritime Code for Dangerous Goods.	
INCI:	International Nomenclature of Cosmetic Ingredients.	
KSt:	Explosion coefficient.	
LC50:	Lethal concentration, for 50 percent of test population.	
LD50:	Lethal dose, for 50 percent of test population.	
LTE:	Long-term exposure.	
PNEC:	Predicted No Effect Concentration.	
RID:	Regulation Concerning the International Transport of Dangerous Goods by Rail.	
STE:	Short-term exposure.	
STEL:	Short Term Exposure limit.	
STOT:	Specific Target Organ Toxicity.	
TLV:	Threshold Limiting Value.	
TWATLV:	Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).	
WGK:	German Water Hazard Class.